Struggle between Lithium Manganese and lithium iron battery power
As the core of electric vehicles, power battery applications with the particularity and complexity. To say, have the last hundred years, not the power battery development is bad, but the oil industry and the automotive industry is too large outstanding technological progress. Power Battery experience in the manufacture of batteries, batteries, battery modules, batteries, four-level links, the whole power system, Laptop battery technology has repeatedly stressed the concept of necessity is: consistency, standardization steps. From a technical achievement levels, ranging from small battery-battery technology upgrade to power, not simply “addition” can be easily reached. Power Battery performance factors (power density, energy density, durability, safety, cost) rings linked, high-power and high energy prices on the development and manufacture of hard to take into account a long time a serious impact on the work of the high-power battery, High-Power exothermic phenomenon of the work of the security of the test battery, energy efficiency must be sacrificed in order to obtain a longer life, high energy density and safety risks. This is technically difficult to obtain a full range of meeting, but only to find a balance, but also with the vehicle fuel system that is the biggest challenge for technology comparison. Route choice in technology, nickel metal hydride batteries, native defects (self-discharge, specific energy is small), it was replaced by lithium batteries, only a matter of time. However, the lithium battery line, a series of disputes can the electrode materials, different systems of lithium manganese oxide have, lithium iron phosphate, nickel-and cobalt-manganese ternary and other technical line. Of the lithium iron phosphate battery technology A123Systems lost Chevrolet tender incidents, automobile manufacturers program the freedom of choice of batteries, for a variety of technical path to wait. We believe that automobile manufacturers’ lithium IBM ThinkPad R40 battery technology is not just over the line, more concerned about the patent dispute, suppliers, manufacturing capabilities and financial strength, etc., it is systemic issues. Main lithium-ion battery makers are still the most commonly used lithium manganese oxide system, Ni-Co-Mn and other technical way, as we believe that given the uncertainty in technological progress, lithium battery technology fronts will be difficult in the 2-3 years will have a clear statement does not preclude the international community, the first benefit of industrialization is the more mature xHEV lithium manganese, nickel, cobalt and other battery-Mn line. Battery is still in the global industrial R & D phase is uncertain, the domestic industry structure and outlook, it is certain that China is in the technical research and development of battery power, battery and vehicle research and development and improve the docking Power battery industry support intensity.
The direction of the battery lithium ion battery that can be in Japan and the United States of lithium-manganese-lithium-divided iron. Lithium manganese battery refers to the lithium manganese oxide cathode materials LiMn2O4 in propulsion. Lithium-iron Dell Latitude D510 battery refers to the lithium iron phosphate as cathode material LiFePO4 Power Battery. Us for a comparison:
Security
Lithium-ion battery charging and discharging process of lithium-ion embedding / de-embedding process. When the crystal structure in the process stability, not change is the battery of security to be high. Otherwise, is that is small, such as the layered structure of the cobalt oxide lithium battery charging voltage rises under the circumstances, the cathode material of lithium ion in the other continued to de-embedded to swim with the cathode, anode material at a time when the filled in the position to the location of the lithium-ion site was, lithium-ion only in the form of metal precipitation on the surface. Such problems arise. On the one hand, the surface of lithium metal deposition is very simple, formed a branch of the form, poly-lithium dendrites, the membrane-penetrating, leading to positive and negative direct short circuit, the other hand, lithium metal is very lively, is a direct response to the electrolyte and heat have, at the same time, the backup lithium is very low, although it is not the surface of the lithium metal dendrite membrane-penetrating, as long as the temperature is slightly higher, as the hp Pavilion DV1000 battery by heating by the discharge of lithium is -melt metal, so that positive and negative short-circuit, causing accidents. There is a high temperature and depth of the charge-discharge process, the cobalt and oxygen bond can be broken to release oxygen and produce an explosion. Lithium cobalt oxide battery temperature of only 150 degrees, the lowest of the three cathode materials. Therefore, the security of the largest lithium cobalt oxide is a short-board batteries.
Lithium manganese spinel crystal battery, lithium-ion embedding / de-embedding process is stable, secure high. The oxidation temperature of 250 degrees of lithium cobalt oxide batteries than a full 100 degrees higher. However, in the depths of the charging and discharging the material lattice Kawasaki (susceptible to changes, especially at the higher temperature), and manganese-oxygen bond can be broken to produce and release oxygen in an explosion. There is also a high temperature lithium-manganese oxide crystals slowly dissolved in the electrolyte problems. Lithium manganese battery and must therefore take a variety of security measures to improve security.
Lithium iron phosphate sony VGP-BPS2A battery is currently the safest battery. Its unique crystal structure of olivine in the phosphate-base for the entire material has a stabilizing effect, makes the material itself has thermal stability and good cycling performance. This is one of the key in the lithium iron phosphate lithium-ion differs from LiCoO2 cathode material of lithium cobalt oxide and lithium manganese LiMn2O4 with a one-dimensional direction of their mobility, the charge-discharge process can undo and be accompanied by extrusion, and move a central metallic iron oxidation and reduction. In addition, the phosphorus-oxygen bond and strong, so lithium batteries short-circuited, it is not because of the short circuit and produce an explosion. The oxidation temperature is higher than 400 degrees, can be placed on the fire. Therefore, increasing the cathode material lithium cobalt oxide and manganese-lithium battery for the safety had to take on a variety of means, while the cathode material lithium iron phosphate is a naturally have security.
Economy
How much do the cobalt to the high price of lithium cobalt oxide material. Manganese is rich in natural resources are cheap, while lighter lithium manganese preparation, manganese-lithium batteries and low cost. Phosphorus and iron-rich cheap, but difficult to lithium iron phosphate preparation for its low rate of sintering of the finished product, so that the material lithium iron phosphate battery costs. To reduce the cost of lithium iron phosphate a variety of methods, such as increased production, improved technology and so on.
High Capacity
Including the electrical power and voltage. Theory of the highest capacity in the lithium-cobalt, manganese and lithium the lowest. However, in order to assess the safety, the actual performance of lithium cobalt oxide of a compromise, only about half the theoretical capacity. Thing like this would, if you have to increase generating capacity to sacrifice safety. Security, high theoretical lithium manganese oxide with a low capacity means that there is not much scope for the development of electric power and up to 148mAh / g VGP-BPS10 with greater safety in comparison, lithium iron phosphate, it was made in the laboratory 160 mAh / g capacity of the actual performance. Of course, the operating voltage of lithium iron phosphate as low as 3.3. But it has a very flat voltage platform, which means it is more stable and efficient discharge properties.
Fast Charge
Speed of charge from the conductive material decision. There is no doubt the worst of lithium iron phosphate. This is because the lithium iron phosphate lithium-ion extrusion, reducing the volume of the grid, from which a total FeO6 octahedron corners, because they can not be separated by oxygen atoms to form a permanent FeO6 network structure, whereby the electronic conductivity. On the other side of the crystal in the oxygen atom near the main road of tightly packed six-party agreement, so that the lithium-ion offers only limited access, allowing lithium ions in the structure at room temperature in a very small migration rates. But that does not mean that lithium manganese oxide can be easily achieved fast loading. Because of its crystal structure of lithium iron phosphate is not stable, high current fast charge may mean that the bars come saki changes, the key of the manganese and oxygen can be broken, which means an explosion. By pair-doped lithium iron phosphate, for example, by adding carbon, cobalt and the like will be the conductivity is greatly increased. BYD experiments reported that his 10 minutes to the apple M8403 battery to 80% are filled.